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- W68469895 abstract "Many physical systems show phase transitions characterized by singularities in one of the thermodynamic potentials, such as the free energy, and hence by discontinuities in their derivatives. The phase transitions are classified according to whether the first, second, or n th derivative of the free energy showed a discontinuity, and they are called first, second, or n th order transitions respectively. As the first derivative of the relevant thermodynamic potential is discontinuous in the case of a first-order phase transition, such a phase transition will usually be accompanied by a latent heat. This chapter concludes with a discussion of the liquid drop model of condensation. The main point of their theory is that as long as for a given temperature the pressure is less than the saturated vapor pressure, most of the gas will consist of single molecules and only a small fraction will be present as small droplets. The number of droplets of a given size rapidly decreases with increasing size. As long as the pressure is below the saturation pressure, the tendency of all drops will be to evaporate rather than to grow, and the larger size drops are present only because of fluctuations." @default.
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- W68469895 date "1995-01-01" @default.
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- W68469895 title "PHASE TRANSITIONS" @default.
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