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- W68537867 abstract "The ready availability of PGA2 from the sea coral Plexaura homomalla, (Esper) makes this substance an attractive starting material for the synthesis of novel prostanoids, Recently, there has been considerable interest in obtaining ring analogues of PGG2, la and PGH2, lb extremely potent but chemically labile substances. These include the 9α, 11α-azo 1c, 9α, 11α -epoxymethano, 1d, 9α, 11α -etheno 1e and 9α, 11α -epoxyimino 1f, analogues of prostaglandin endoperoxide, as well as the acetal of PGF2. Shown to retain biological potency, the acetal is particularly interesting for it demonstrates that endoperoxide mimicry is not restricted to the heterobicyclo [2,2,1] heptane system. The 9α, llα -trithiocarbonate of 9α, 11α -bisdesoxy PGF2 was synthesized starting from PGA2. Preliminary tests for biological activity in systems which are responsive to the prostaglandins endoperoxides were conducted on this novel analogue." @default.
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- W68537867 date "1979-01-01" @default.
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- W68537867 title "THE SYNTHESIS AND BIOLOGICAL PROPERTIES OF 9α, 11α-TRITHIO-CARBONATE OF 9, 11α-BISDESOXY-PGF2. A MIMIC OF PROSTAGLANDIN ENDOPEROXIDES" @default.
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