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- W70290074 abstract "ABSTRACT Transitional entropies of smectic A-nematic, smectic A-cholesteric and smectic A-isotropic phase transitions were measured by differential scanning calorimetry (DSC) in different binary mixtures the components of which were selected by the Kofler contact method. Non-ideal behaviour was found only for smectic phases in which maxima could be detected. Transitional entropy values of smectic A-nematic and smectic A-cholesteric transitions were used in an estimation of A-B pair interaction energies in the form of differences of the chemical potentials in different phases compared with the known intermolecular interaction energies of the same substituents in associates (H-bridge). The estimated interaction energies seem to be inadequate for the charge-transfer-complex model; instead, a simple solvation-in-layer process is suggested." @default.
- W70290074 created "2016-06-24" @default.
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- W70290074 date "1981-01-01" @default.
- W70290074 modified "2023-09-29" @default.
- W70290074 title "Studies on induced smectic A phases, I. Transitional entropies of binary mixtures of smectogenes and cholesterogenes" @default.
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- W70290074 doi "https://doi.org/10.1016/b978-1-4831-1775-1.50025-8" @default.
- W70290074 hasPublicationYear "1981" @default.
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