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- W70831154 abstract "A numerical model has been used to study photochemical enhancement of laminar, fuel-lean H2-air flames. Flame speed, temperature, and species concentrations have been calculated by solving the one-dimensional time-dependent conservation equations with a detailed mechanism for H2 oxidation. To examine the effect of irradiation on the propagating flame, unimolecular photodissociation reactions were incorporated into the kinetic scheme. They simulated the photodissociation of O2 or HO2 with vacuum ultraviolet or ultraviolet irradiation, respectively. Combustion enhancement has been determined in terms of increases in flame speed. Significant increases have been calculated, as much as 62% over the comparable value without irradiation. The radical deposition achieved by photodissociation alters the balance between chain branching and termination, producing higher radical concentrations, especially in the critical induction zone. The resulting increases in the rate of fuel consumption are evident in the higher calculated flame speeds. The rate and position of radical deposition are key factors in the enhancement obtained." @default.
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- W70831154 date "1987-02-24" @default.
- W70831154 modified "2023-09-27" @default.
- W70831154 title "Analytical modeling of enhancement of premixed H2/air flames with photochemically produced radicals" @default.
- W70831154 hasPublicationYear "1987" @default.
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