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- W71297519 abstract "The catalytic and radiation polymerization of allylsilanes containing the Si--H bond were investigated. Benzoyl peroxide and platinized carbon were used as catalysts; irradiation was carried out with gamma and BETA rays. Monoallylsilanes polymerize to viscous liquids. The products of the polymerization of diallylsilanes are powders. The principal relations of catalytrc polymerization were shown to hold also for radiation polymerization. The radiation copolymerization of various allylsrlane derivatives containing Si-- H bonds with acrylonitrile and styrene was studied. lt was Shown that a small percentage of organosilicon compounds in copolymerization with styrene change the physical properties of polystyrene. An examination of the infrared spectra showed that the Si--H bond remained in all the resultant polymers and copolymers, the least amounts berng preserved in the homopolymers. In the latter the double bond is also consumed. The ESR spectra of the polymers and copolymers were investigated. (tr-auth)" @default.
- W71297519 created "2016-06-24" @default.
- W71297519 date "1962-01-01" @default.
- W71297519 modified "2023-09-25" @default.
- W71297519 title "Catalytic and radiation polymerization and copolymerization of allylhydrosilanes" @default.
- W71297519 doi "https://doi.org/10.1016/0032-3950(62)90522-1" @default.
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