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- W71392020 abstract "Interactions between linear synthetic macromolecules containing complementary functional groups (for example, basic and acidic) have a well-expressed cooperative character and result in polymer-polymer complexes being formed. The cooperativity shows itself in a strong shift of the equilibria towards complex formation compared to the low molecular analogues, in the critical character of the dependence of the stability of the polycomplexes upon the chain lengths of the components, and also in the peculiarities of the distribution of oligomers along macromolecular templates. Complex formation between macromolecules is a structure-sensitive reaction. Sometimes it is accompanied by conformational transitions of polymer reagents. For example, one of the macromolecules may be ‘forced’ to acquire a conformation which it would not assume in the given conditions in the absence of the polymer partner (this is exemplified by ionogenic polypeptides altering the secondary structure). In most cases complex formation results in compact tertiary structures which seem to play an important role in the stabilization of the complexes." @default.
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- W71392020 date "1973-01-01" @default.
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- W71392020 title "THE COOPERATIVE INTERACTIONS OF COMPLEMENTARY SYNTHETIC MACROMOLECULES IN SOLUTIONS" @default.
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- W71392020 doi "https://doi.org/10.1016/b978-0-408-70516-5.50010-6" @default.
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