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- W71648628 abstract "SUMMARY Neutral or cationic dinuclear complexes of rhodium(I), [Rh 2 X 2 (CO) (μ-Ph 2 -PCH 2 PPh 2 ) 2 ] or [Rh 2 (μ-YXCO) (μ-Ph 2 PCH 2 PPh 2 ) 2 ] + (X,Y=Cl,I,CN; n = 2–4) and related complexes, are efficient catalysts for the sequential hydrogenation of alkynes to alkenes and alkanes under an atmosphere of hydrogen alone. Under an atmosphere of hydrogen and carbon monoxide these catalysts are highly selective for hydrogenation of alkynes to alkenes. At elevated temperatures these complexes are also active for the hydroformylation of alkenes to aldehydes, ketones, cyclic ketones, or acetals. The product distribution is dependant upon the precise nature of the catalyst, the solvent, reaction temperature, and proportion of reagents. In methanol a sequence of reactions occurs in which the product aldehyde forms an acetal, ether, and finally a product containing a methylene group generated from the CO inserted in the hydroformylation reaction." @default.
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- W71648628 date "1988-01-01" @default.
- W71648628 modified "2023-09-28" @default.
- W71648628 title "Dinuclear Complexes of Rhodium as Catalysts For the Reactions of Alkenes with Carbon Monoxide and Hydrogen" @default.
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- W71648628 doi "https://doi.org/10.1016/s0167-2991(09)60680-7" @default.
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