Matches in SemOpenAlex for { <https://semopenalex.org/work/W71920006> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W71920006 abstract "The reactions of W(OR)/sub 6/ (I), WO(OR)/sub 4/ (II), and WO/sub 2/(OR)/sub 2/ with NaOR (R = Et) have been studied with the aid of conductometric titrations. The titration curves of II and III have end-points at an Na:W ratio equal to 1:1, and in the latter case, complexation takes place with time. The solubility in the NaOR-WO(OR)/sub 4/-ROH (I) and Bi(OR)/sub 3/-WO(OR)/sub 3/-ROH (II) systems at 25/sup 0/C has been studied. The formation of the crystalline complex NaWO(OR)/sub 5/ (IV), which is highly soluble in ethanol (approx. 40%) and has T/sub m/ = 70-80/sup 0/C, has been discovered in system I. In system II there are crystallization branches of the components and a homogeneous region between the 3:2 and 1:1 compositions. According to the IR-spectroscopic data, the complexation process of II is accompanied by cleavage of the W...O...W. bridges. A set of interplanar distances has been presented for complex IV. In contrast to the case of nonvolatile WO/sub 2/(OR)/sub 2/, following the thermolysis of NaWO/sub 2/(OR)/sub 3/, fragmentation products of W(OR)/sub 6/, which apparently form as a result of disproportionation of the complex, have been detected mass-spectrometrically in the gaseous phase." @default.
- W71920006 created "2016-06-24" @default.
- W71920006 creator A5043928569 @default.
- W71920006 creator A5065412531 @default.
- W71920006 date "1988-06-01" @default.
- W71920006 modified "2023-09-26" @default.
- W71920006 title "Bimetallic alkoxides of tungsten (VI)" @default.
- W71920006 hasPublicationYear "1988" @default.
- W71920006 type Work @default.
- W71920006 sameAs 71920006 @default.
- W71920006 citedByCount "0" @default.
- W71920006 crossrefType "journal-article" @default.
- W71920006 hasAuthorship W71920006A5043928569 @default.
- W71920006 hasAuthorship W71920006A5065412531 @default.
- W71920006 hasConcept C113196181 @default.
- W71920006 hasConcept C115624301 @default.
- W71920006 hasConcept C147789679 @default.
- W71920006 hasConcept C155574463 @default.
- W71920006 hasConcept C161790260 @default.
- W71920006 hasConcept C17365422 @default.
- W71920006 hasConcept C178790620 @default.
- W71920006 hasConcept C179104552 @default.
- W71920006 hasConcept C184866935 @default.
- W71920006 hasConcept C185592680 @default.
- W71920006 hasConcept C43411465 @default.
- W71920006 hasConcept C43617362 @default.
- W71920006 hasConcept C542268612 @default.
- W71920006 hasConcept C544153396 @default.
- W71920006 hasConcept C55493867 @default.
- W71920006 hasConcept C61276311 @default.
- W71920006 hasConcept C8010536 @default.
- W71920006 hasConceptScore W71920006C113196181 @default.
- W71920006 hasConceptScore W71920006C115624301 @default.
- W71920006 hasConceptScore W71920006C147789679 @default.
- W71920006 hasConceptScore W71920006C155574463 @default.
- W71920006 hasConceptScore W71920006C161790260 @default.
- W71920006 hasConceptScore W71920006C17365422 @default.
- W71920006 hasConceptScore W71920006C178790620 @default.
- W71920006 hasConceptScore W71920006C179104552 @default.
- W71920006 hasConceptScore W71920006C184866935 @default.
- W71920006 hasConceptScore W71920006C185592680 @default.
- W71920006 hasConceptScore W71920006C43411465 @default.
- W71920006 hasConceptScore W71920006C43617362 @default.
- W71920006 hasConceptScore W71920006C542268612 @default.
- W71920006 hasConceptScore W71920006C544153396 @default.
- W71920006 hasConceptScore W71920006C55493867 @default.
- W71920006 hasConceptScore W71920006C61276311 @default.
- W71920006 hasConceptScore W71920006C8010536 @default.
- W71920006 hasLocation W719200061 @default.
- W71920006 hasOpenAccess W71920006 @default.
- W71920006 hasPrimaryLocation W719200061 @default.
- W71920006 hasRelatedWork W2014874909 @default.
- W71920006 hasRelatedWork W2024091790 @default.
- W71920006 hasRelatedWork W2238888340 @default.
- W71920006 hasRelatedWork W2255639425 @default.
- W71920006 hasRelatedWork W2328277775 @default.
- W71920006 hasRelatedWork W2786962576 @default.
- W71920006 hasRelatedWork W2800269644 @default.
- W71920006 hasRelatedWork W2949110139 @default.
- W71920006 hasRelatedWork W2950451277 @default.
- W71920006 hasRelatedWork W2950474936 @default.
- W71920006 hasRelatedWork W2952715740 @default.
- W71920006 hasRelatedWork W3002611070 @default.
- W71920006 hasRelatedWork W3099099194 @default.
- W71920006 hasRelatedWork W3136532786 @default.
- W71920006 hasRelatedWork W3137250635 @default.
- W71920006 hasRelatedWork W3161811777 @default.
- W71920006 hasRelatedWork W3188441733 @default.
- W71920006 hasRelatedWork W3194954063 @default.
- W71920006 hasRelatedWork W1660021546 @default.
- W71920006 hasRelatedWork W2243845537 @default.
- W71920006 isParatext "false" @default.
- W71920006 isRetracted "false" @default.
- W71920006 magId "71920006" @default.
- W71920006 workType "article" @default.