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- W72097795 abstract "Methanol protonates various carbenes to give carbocations. Examples include the nucleophilic cycloheptatrienylidene as well as vinylcarbenes and phenylcarbene. 3-Cyclopentenylidene, generated by Skattebøl rearrangement, produces nonplanar 3-cyclopentenyl = bishomocyclopropenyl cations. - Recent studies on aliphatic diazonium ions confirm Streitwieser's postulate of competing reaction paths. In specific cases, such as endo-2-norbornyl, neighboring group participation may be more prominent in deamination than in solvolysis.- 1, 2-Alkyl shifts of many acyclic carbocations proceed by way of alkyl-bridged intermediates. The criteria distinguishing open and bridged ions include the stereochemistry at the migration origin, the regioselectivity of sequential rearrangements, and intramolecular proton shifts of protonated cyclopropanes. In the bicyclic series, the 2-bicyclo[2.1.1]hexyl cation is more revealing than 2-norbornyl with regard to the nonclassical ion problem." @default.
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- W72097795 date "1984-01-01" @default.
- W72097795 modified "2023-10-16" @default.
- W72097795 title "GENERATION AND REACTIVITY OF CARBOCATIONS" @default.
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- W72097795 doi "https://doi.org/10.1016/b978-0-08-029249-6.50032-5" @default.
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