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- W72133696 abstract "Study of the kinetics of sulfur dioxide oxidation by iron(III) (the systems FeCl/sub 3/-HClO/sub 4/-H/sub 2/O,FeCl/sub 3/-HClO/sub 4/-Kl-H/sub 2/O, and FeCl/sub 3/-HClO/sub 4/-LiCl-H/sub 2/O) showed that the introduction of iodide and chloride ions raises the activity of the system. The proposed mechanism of oxidation postulates the formation of the thionate radical (HSO/sub 3/). The reaction order was determined to be 1 with respect to the oxidizing and reducing agents and iodide ions, and 0.5 with respect to chloride ions. The calculated activation energies were determine to be 68.9 kJ/mole (H/sub 2/O), 44.0 kJ/mole (with chloride ions), and 37.5 kJ/mole (with iodide ions)." @default.
- W72133696 created "2016-06-24" @default.
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- W72133696 date "1982-07-10" @default.
- W72133696 modified "2023-09-26" @default.
- W72133696 title "Catalytic oxidation of sulfur dioxide by complex compounds of iron(III)" @default.
- W72133696 hasPublicationYear "1982" @default.
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