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- W72372912 abstract "This chapter presents an expansion of the concept of bridging, which extends canonical nomenclature to compounds in which the union of two or more cycles is either a single atom, a single edge, or when a succession of edges connect otherwise unconnected cycles. Four important different protocols suggested by such an extension include: (1) a system of nomenclature modeled on spherical coordinates. (2) a modification of this system called sandwich nomenclature for metallocenes; (3) consideration of a cyclic compound in terms of its largest spanning tree, which is then supplemented by the set of edges that had been removed to form that tree; and (4) use of redundant paths to cover all of the atoms and bonds of the molecule. These latter two techniques are important both for spiro-molecules in which the rings containing the common atom are of different constitution and for ring assembly compounds. Additionally, in many instances, the other distinct types of nomenclature that are introduced earlier may be interconverted in the same way, as the different types of coordinate systems in geometry may be interconverted. The choice of an optimal name for a given molecule is based on the heuristic principles of shortness and simplicity." @default.
- W72372912 created "2016-06-24" @default.
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- W72372912 date "2005-01-01" @default.
- W72372912 modified "2023-09-26" @default.
- W72372912 title "Spiro and related compounds" @default.
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- W72372912 doi "https://doi.org/10.1016/b978-044451685-5/50006-8" @default.
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