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- W72890769 abstract "The model of a two-nuclear radical pair has been applied to describe the formation of the magnetic field effects experimentally observed by C. Evans and J. C. Scaiano in the micellar photoinduced electron transfer reaction of α-terthienyl and metyl viologen. The model takes into account diffusional motion on the surface of micelle under spin motion, spin-selective recombination, and first-order process of irreversible exit. The stochastic Liouville equation has been solved by the finite difference method. The dresults of the calculations quantitatively agree with the experiment. It has been shown that comparison of the experimental and calculated magnetic field effects leads to a reasonable estimation of the micellar surface diffusion coefficient.Key words Micelles magnetic effect photoinduced electron transfer α-terthienyl methyl viologen" @default.
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- W72890769 date "2007-12-10" @default.
- W72890769 modified "2023-09-26" @default.
- W72890769 title "Spin-controlled reactions on the micellar surface" @default.
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- W72890769 doi "https://doi.org/10.1007/bfb0115949" @default.
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