Matches in SemOpenAlex for { <https://semopenalex.org/work/W7303074> ?p ?o ?g. }
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- W7303074 abstract "Abstract The concepts of the so-called interfacial coordination chemistry (ICC) are established for complexes interacting with oxide surfaces and involving transition metal ions (TMIs). The latter can function either as probes of their own interaction with the oxide surface, as adsorption and/or catalytic sites or as precursors of oxide-supported metal particles in mono or polymetallic systems. The concepts of ICC are compared with those of solution and solid state coordination chemistries and a general classification of the different coordination chemistry types is proposed. The analogies and differences are stressed and concern the mobility, accessibility and reactivity of the transition metal complexes. Those parameters, which are largely dependent on the bonding strength of the TMI with the oxide support and in turn on the role of the oxide support and choice of the preparation method, determine the catalytic properties. Examples of catalytic reactions will be given which involve the oligomerisation of olefins and the oxidation of methanol and can be described at a molecular level. Finally, the importance of the bonding strength of TMIs with the oxide support will be stressed in determining the preparation and properties of small supported metal particles which exhibit a strong memory effect with respect to their oxidized precursor state. The present molecular approach suggests that both the preparation and catalytic phenomena can be seen in a more predictive manner and that more effort should be devoted in the future to fundamental research in this area." @default.
- W7303074 created "2016-06-24" @default.
- W7303074 creator A5003839600 @default.
- W7303074 date "1993-01-01" @default.
- W7303074 modified "2023-10-11" @default.
- W7303074 title "Interfacial Coordination Chemistry: Concepts and Relevance to Catalysis Phenomena" @default.
- W7303074 cites W105949552 @default.
- W7303074 cites W1410759920 @default.
- W7303074 cites W141246696 @default.
- W7303074 cites W1512695912 @default.
- W7303074 cites W1578707808 @default.
- W7303074 cites W1638760679 @default.
- W7303074 cites W1795524456 @default.
- W7303074 cites W1963629908 @default.
- W7303074 cites W1965129522 @default.
- W7303074 cites W1966497735 @default.
- W7303074 cites W1967491988 @default.
- W7303074 cites W1972078537 @default.
- W7303074 cites W1972122068 @default.
- W7303074 cites W1972991191 @default.
- W7303074 cites W1976331149 @default.
- W7303074 cites W1977539024 @default.
- W7303074 cites W1979893459 @default.
- W7303074 cites W1982996242 @default.
- W7303074 cites W1984075453 @default.
- W7303074 cites W1984456833 @default.
- W7303074 cites W1986538035 @default.
- W7303074 cites W1987040073 @default.
- W7303074 cites W1988292301 @default.
- W7303074 cites W1989878456 @default.
- W7303074 cites W1992637340 @default.
- W7303074 cites W1993294961 @default.
- W7303074 cites W1994537892 @default.
- W7303074 cites W1996157045 @default.
- W7303074 cites W1997559545 @default.
- W7303074 cites W1998868867 @default.
- W7303074 cites W1999399856 @default.
- W7303074 cites W1999537827 @default.
- W7303074 cites W2000906547 @default.
- W7303074 cites W2001902106 @default.
- W7303074 cites W2003321638 @default.
- W7303074 cites W2004049322 @default.
- W7303074 cites W2008980052 @default.
- W7303074 cites W2011663526 @default.
- W7303074 cites W2011844291 @default.
- W7303074 cites W2012474307 @default.
- W7303074 cites W2014044211 @default.
- W7303074 cites W2020252820 @default.
- W7303074 cites W2022495217 @default.
- W7303074 cites W2026603224 @default.
- W7303074 cites W2028020885 @default.
- W7303074 cites W2028712320 @default.
- W7303074 cites W2034329598 @default.
- W7303074 cites W2034906076 @default.
- W7303074 cites W2038107317 @default.
- W7303074 cites W2038938117 @default.
- W7303074 cites W2040578224 @default.
- W7303074 cites W2042536439 @default.
- W7303074 cites W2042993674 @default.
- W7303074 cites W2047092961 @default.
- W7303074 cites W2047737192 @default.
- W7303074 cites W2047963193 @default.
- W7303074 cites W2048535866 @default.
- W7303074 cites W2050286785 @default.
- W7303074 cites W2051386757 @default.
- W7303074 cites W2051594340 @default.
- W7303074 cites W2051806683 @default.
- W7303074 cites W2052438045 @default.
- W7303074 cites W2052536213 @default.
- W7303074 cites W2054409449 @default.
- W7303074 cites W2056018403 @default.
- W7303074 cites W2056575643 @default.
- W7303074 cites W2057444473 @default.
- W7303074 cites W2057806729 @default.
- W7303074 cites W2058098574 @default.
- W7303074 cites W2058306137 @default.
- W7303074 cites W2061266490 @default.
- W7303074 cites W2063678980 @default.
- W7303074 cites W2064276865 @default.
- W7303074 cites W2066308439 @default.
- W7303074 cites W2072913985 @default.
- W7303074 cites W2073038641 @default.
- W7303074 cites W2078602479 @default.
- W7303074 cites W2079147420 @default.
- W7303074 cites W2083195058 @default.
- W7303074 cites W2083532020 @default.
- W7303074 cites W2086162111 @default.
- W7303074 cites W2089790324 @default.
- W7303074 cites W2091341867 @default.
- W7303074 cites W2091985295 @default.
- W7303074 cites W2093141808 @default.
- W7303074 cites W2093340950 @default.
- W7303074 cites W2094199132 @default.
- W7303074 cites W2095260755 @default.
- W7303074 cites W2099703449 @default.
- W7303074 cites W2110323465 @default.
- W7303074 cites W2124833563 @default.
- W7303074 cites W2135961547 @default.