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- W73224305 abstract "Publisher Summary This chapter discusses the effect of monomolecular films on the surface temperature of water. It presents a method for using a thermistor to estimate the temperature of a surface layer of water during studies of the effect of insoluble monolayers on evaporation. The surface temperature was shown to be sensitive to changes in the rate of evaporation and easily adopted to use with a Langmuir–Adam film balance. The temperature of a clean water surface in contact with an atmosphere of low relative humidity was found to be at least 7°C cooler than the thermostatted room temperature and to rise almost to room temperature when an insoluble monolayer of high specific resistance to evaporation was adsorbed thereon. The equilibrium surface temperature was a reversible function of the film pressure under the experimental conditions studied. The maximum surface temperature of water attained with a compressed monomolecular film was shown to be a sensitive function of molecular structure. Any variation in molecular structure that prevented close-packing of the hydrocarbon chains such as the presence of unsaturation, ionized polar groups, or the replacement of an aliphatic hydrogen atom by a larger substituent greatly reduced its effectiveness as a barrier to evaporation. Evaporation resistance was found to be more related to those factors determining intermolecular cohesion such as the length of the hydrocarbon chain than to the nature of the polar hydrophilic group." @default.
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- W73224305 date "1962-01-01" @default.
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- W73224305 title "The Effect of Monomolecular Films on the Surface Temperature of Water" @default.
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- W73224305 doi "https://doi.org/10.1016/b978-1-4832-2947-8.50008-2" @default.
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