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• W74051091 abstract "Abstract Lithium-ion (Li-ion) cells may smoke when abused and can ignite when the abuse is extreme. Thermal stability is a basic problem as regards cell safety. Several exothermic reactions occur inside a cell as its temperature increases. It is generally considered that “thermal runaway” occurs if heat output exceeds thermal diffusion. Possible exothermic reactions are: (1) chemical reduction of the electrolyte by the anode, (2) thermal decomposition of the electrolyte and (3) oxidation of the electrolyte on the cathode. Thermal stability of graphite anode, silicon/Li alloy anode, LiPF 6 /Alkyl carbonate mixed-solvent electrolytes, LiPF 6 /methyl difluoroacetate electrolyte, LiCoO 2 cathode and FeF 3 cathode with 1 M LiPF 6 /EC + DMC were investigated using DSC. Charged graphite anode and silicon/Li alloy anode showed almost the same heat output based on the amount of Li in each anode. LiPF 6 /methyl difluoroacetate electrolyte and FeF 3 cathode showed a very small heat output." @default.
• W74051091 created "2016-06-24" @default.
• W74051091 creator A5050285198 @default.
• W74051091 date "2014-01-01" @default.
• W74051091 modified "2023-09-23" @default.
• W74051091 title "Thermal Stability of Materials in Lithium-Ion Cells" @default.
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• W74051091 doi "https://doi.org/10.1016/b978-0-444-59513-3.00020-0" @default.
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