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- W74162480 abstract "The use of jet fuel as a heat exchange medium imposes significant levels of thermal stress. Hydrocarbon fuels subjected to such temperatures have been shown to undergo considerable degradation. This observed degradation can be manifested by the formation of deposits on heat exchanger surfaces, on filters, in nozzles and on combustor surfaces. Heteroatoms, i.e., oxygen, nitrogen and sulfur and ash have been found to comprise as much as 40% of such deposits. It is difficult to identify specific reaction pathways from studies of fuels, which are complex mixtures. Model studies have been utilized to determine trace reaction products. These model studies were conducted in sealed borosilicate glass tubes at 120{degree}C for up to 60 min. From the t-butylhydroperoxide (tBHP) initiated oxidation of dodecane thiol and hexyl sulfide the major oxidation products were the dodecyl disulfide and hexyl sulfoxide, respectively. Similar studies revealed the major product of the oxidation of thiophenol by tBHP or oxygen to be phenyl disulfide. The authors have utilized their modified JFTOT apparatus as a first step in determining the applicability of the findings from the model studies with changes occurring in aircraft fuel systems. This paper describes studies of the oxidation of thiophenol and hexyl disulfidemore » in dodecane during stress in the JFTOT.« less" @default.
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- W74162480 date "1989-01-01" @default.
- W74162480 modified "2023-09-26" @default.
- W74162480 title "Oxidation of selected organosulfur compounds in dodecane over a heated metal surface" @default.
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