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- W7465666 abstract "Thorium oxide in aqueous slurries catalyzes the hydrolysis of Na/sub 4/P/ sub 2/O/sub 7/ to the orthophosphate. In the initial stages of the hydrolysis, the rate is propertioral to the ThO/sub 2/ concentration, but this effect rapidly diminishes with time, probably due to the inhibiting effect of orthophosphate adsorbed on the catalyst. The time required for a definite fraction of complete reaction to occur is relatively independent of the initial concentration of Na/ sub 4/P/sub 2/O/sub 7/, thus indicating that the hydrolysis is of the first order with respect to pyrophosphate. Over the range of temperature of 25 to 100 deg C, the rate of hydrolysis increases approximately 3fold for each l0 deg increase in temperature. An activation energy of 20 kcal per mole was calculated for this reaction. (auth)" @default.
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- W7465666 date "1960-03-01" @default.
- W7465666 modified "2023-09-27" @default.
- W7465666 title "CATALYZED HYDROLYSIS OF PYROPHOSPHATE BY THORIUM OXIDE" @default.
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