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• W748341749 endingPage "8032" @default.
• W748341749 startingPage "8026" @default.
• W748341749 abstract "Herein, it is the first report that a cathodic electrochemiluminescence (ECL) resonance energy transfer (ERET) system is fabricated by layer-by-layer (LBL) electrostatic assembly of CoAl layered double hydroxide (LDH) nanosheets with a mixture of blue BSA–gold nanoclusters (AuNCs) and Ru(bpy)32+ (denoted as AuNCs@Ru) on an Au electrode. The possible ECL mechanism indicates that the appearance of CoAl–LDH nanosheets generates a long-range stacking order of the AuNCs@Ru on an Au electrode, facilitating the occurrence of the ERET between BSA–AuNC donors and Ru(bpy)32+ acceptors on the as-prepared AuNCs@Ru–LDH ultrathin films (UTFs). Furthermore, it is observed that the cathodic ECL intensity can be quenched efficiently in the presence of 6-mercaptopurine (6-MP) in a linear range of 2.5–100 nM with a detection limit of 1.0 nM. On the basis of these interesting phenomena, a facile cathodic ECL sensor has successfully distinguished 6-MP from other thiol-containing compounds (e.g., cysteine and glutathione) in h..." @default.
• W748341749 created "2016-06-24" @default.
• W748341749 creator A5019491876 @default.
• W748341749 creator A5040858696 @default.
• W748341749 creator A5050029948 @default.
• W748341749 date "2015-07-22" @default.
• W748341749 modified "2023-10-15" @default.
• W748341749 title "Gold Nanoclusters@Ru(bpy)₃²⁺-Layered Double Hydroxide Ultrathin Film as a Cathodic Electrochemiluminescence Resonance Energy Transfer Probe" @default.
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• W748341749 doi "https://doi.org/10.1021/acs.analchem.5b02208" @default.
• W748341749 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26159772" @default.
• W748341749 hasPublicationYear "2015" @default.
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