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- W75164401 abstract "This project was inspired by an industrial visit to a company based in the Gold Coast,Brisbane in 2005, where luxury yachts, cruisers and flybridge convertibles aremanufactured. In the production of such water vehicles and other fibre-reinforced plastics,styrene, a volatile organic compound, is often a fugitive airborne pollutant. Thetoxicological effects of styrene have been studied to some extent, and are recognized tohave potentially carcinogenic effects.Photocatalysis presents a sustainable alternative to the traditional methods of pollutantcontroltechnologies, and can be used in the control of styrene emissions.This treatise focuses on the synthesis and characterization of photocatalysts which aresuitable for photo-oxidizing styrene in a custom-designed, annular fluidized-bedphotoreactor. Both UV and visible-light responsive photocatalysts have been developedand used to degrade 300ppmV of airborne styrene under various flowrates and relativehumidity levels. These photoresponsive materials include titania-pillared clay basedmaterials, P25-based materials, fluorine-doped or fluorocarbon-functionalized titaniamicrospheres, and Bi/BiO nanoparticles supported on (Nb-Ti-Si) oxide.Titania-pillared clay is found to maintain the anatase-TiO2 structure fully when exposedto 1200oC for 6 hours, and a model has been proposed to account for this phenomenon.On the other hand, fluorocarbon-functionalized titania microspheres are found to be ableto degrade styrene fully under both UV and visible light, and this is partly attributed tothe electron-scavenging properties of the electrophillic fluorocarbon groups on thesurfaces of the material.Reaction intermediates arising from the photooxidation reactions have also beenidentified, and include benzaldehyde, benzene, benzyl alcohol, benzoic acid,dimethylacetylbenzene, hydroquinone and phenol." @default.
- W75164401 created "2016-06-24" @default.
- W75164401 creator A5017678158 @default.
- W75164401 date "2008-07-01" @default.
- W75164401 modified "2023-09-27" @default.
- W75164401 title "Nanostructured Photocatalysts for the Destruction of Styrene" @default.
- W75164401 hasPublicationYear "2008" @default.
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