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- W752077822 abstract "The charge-transfer complexation between octathia-24-crown-8 (OT24C8) and iodine in chloroform solution was studied spectrometrically at various temperatures. The molar absorptivities and formation constants of the resulting 1:1 complex were determined. The formation of the OT24C8-I 2 complex was also confirmed by H NMR spectrometry. The enthalpy and entropy of the charge-transfer complexation were determined from the temperature dependence of the formation constant, as ΔH° = -31.0 ′ 0.5 kJ mol - 1 and ΔS° = -84 ′ 6 J mol - 1 K - 1 ." @default.
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- W752077822 date "2004-01-01" @default.
- W752077822 modified "2023-09-26" @default.
- W752077822 title "Spectroscopic Studies of charge-transfer Complexation of Octathia-24-crown-8 with Iodine in Chloroform Solution" @default.
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