FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W755501454> ?p ?o ?g. }

• W755501454 endingPage "110" @default.
• W755501454 startingPage "94" @default.
• W755501454 abstract "The binary phase diagrams {V,Nb,Ta}-Sb below 1450 °C were studied by means of XRPD, EPMA, and DTA measurements. In the V-Sb system, five stable binary phases were observed in this investigation: V3+xSb1−x, ℓT-V3Sb2, hT-V2−xSb, V7.46Sb9, V1−xSb2. The V-Sb phase diagram is characterized by two degenerate eutectic reactions: L↔V3+xSb1−x+(V) (T > 1450 °C at 18.1 at.% Sb) and L↔V1−xSb2+(Sb) (T=(621 ± 5)°C at ∼99 at.% Sb), three peritectic reactions: L + V3+xSb1−x↔hT-V2−xSb (T=(1230 ± 10)°C at ∼42 at.% Sb), L + hT-V2−xSb↔V7.46Sb9 (T=(920 ± 10)°C at ∼87 at.% Sb), and L + V7.46Sb9↔V1−xSb2 (T=(869 ± 5)°C at ∼88 at.% Sb), a peritectoid reaction: V3+xSb1−x + hT-V2−xSb↔ℓT-V3Sb2 at (875 ± 25)°C, a eutectoid reaction: hT-V2−xSb↔ℓT-V3Sb2+V7.46Sb9 at (815 ± 15)°C and congruent melting of V3+xSb1−x (T > 1450 °C). An X-ray single crystal study of V5Sb4C1−x proved the existence of interstitial elements in the octahedral voids of a partially filled Ti5Te4-type structure (x∼0.5; RF2 = 0.0101), therefore this phase (earlier labeled “V5Sb4”) was excluded from the binary equilibrium phase diagram. V5Sb4C1−x is the first representative of a filled Ti5Te4-type structure. A re-investigation of the Nb-Sb system removed the contradiction between the hitherto reported phase diagrams and confirmed the version derived by Melnyk et al. (see ref. [1]). Three binary phases exist in the Ta-Sb system: Ta3+xSb1−x, Ta5Sb4, TaSb2. Due to instrumental limits (≤1450 °C), only the peritectic reaction of TaSb2: L + Ta5Sb4 ↔ TaSb2 ((1080 ± 10)°C at ∼92 at.% Sb) and a degenerate Sb-rich eutectic reaction (L↔TaSb2+(Sb); (622 ± 5)°C; ∼99 at.% Sb) have been determined. Physical properties (mechanical and transport properties) of binary di-antimonides were investigated with respect to a potential use of these metals either as diffusion barriers or electrodes for thermoelectric devices based on skutterudites. All group-V metal di-antimonides have low metallic-type resistivity and relatively high thermal conductivity. Magnetic field has little influence on the resistivity of V1−xSb2 at low temperature, while on {Nb,Ta}Sb2 it increases the resistivity, especially on NbSb2. The coefficient of thermal expansion (CTE) decreases from V1−xSb2 to TaSb2, particularly the CTE value of NbSb2 is in the range of average n-type filled skutterudites. In contrast to the CTE value, elastic moduli increase from V1−xSb2 to TaSb2. The value for V1−xSb2 is in the range of Sb-based skutterudites, whereas the values for {Nb,Ta}Sb2 are significantly higher." @default.
• W755501454 created "2016-06-24" @default.
• W755501454 creator A5007336688 @default.
• W755501454 creator A5024114335 @default.
• W755501454 creator A5028607728 @default.
• W755501454 creator A5037250149 @default.
• W755501454 creator A5039996379 @default.
• W755501454 creator A5047897531 @default.
• W755501454 creator A5060358335 @default.
• W755501454 creator A5068082042 @default.
• W755501454 creator A5072820678 @default.
• W755501454 creator A5084461306 @default.
• W755501454 creator A5085461814 @default.
• W755501454 creator A5087243487 @default.
• W755501454 date "2015-10-01" @default.
• W755501454 modified "2023-10-16" @default.
• W755501454 title "Constitution of the systems {V,Nb,Ta}-Sb and physical properties of di-antimonides {V,Nb,Ta}Sb2" @default.
• W755501454 cites W160268837 @default.
• W755501454 cites W1615848898 @default.
• W755501454 cites W1964261031 @default.
• W755501454 cites W1964905444 @default.
• W755501454 cites W1966097869 @default.
• W755501454 cites W1974104118 @default.
• W755501454 cites W1980211358 @default.
• W755501454 cites W1982590801 @default.
• W755501454 cites W1985235886 @default.
• W755501454 cites W1991000655 @default.
• W755501454 cites W1995997336 @default.
• W755501454 cites W2003324923 @default.
• W755501454 cites W2004318959 @default.
• W755501454 cites W2013631723 @default.
• W755501454 cites W2014406868 @default.
• W755501454 cites W2015872606 @default.
• W755501454 cites W2022315858 @default.
• W755501454 cites W2023967860 @default.
• W755501454 cites W2031930638 @default.
• W755501454 cites W2036197280 @default.
• W755501454 cites W2045360097 @default.
• W755501454 cites W2048523261 @default.
• W755501454 cites W2057338083 @default.
• W755501454 cites W2059290024 @default.
• W755501454 cites W2059374366 @default.
• W755501454 cites W2063334178 @default.
• W755501454 cites W2067793015 @default.
• W755501454 cites W2074600111 @default.
• W755501454 cites W2092142998 @default.
• W755501454 cites W2092707196 @default.
• W755501454 cites W2093057277 @default.
• W755501454 cites W2094300597 @default.
• W755501454 cites W2104256072 @default.
• W755501454 cites W2131350133 @default.
• W755501454 cites W2317894704 @default.
• W755501454 cites W2319950183 @default.
• W755501454 cites W2949421488 @default.
• W755501454 cites W2953005133 @default.
• W755501454 doi "https://doi.org/10.1016/j.intermet.2015.05.006" @default.
• W755501454 hasPublicationYear "2015" @default.
• W755501454 type Work @default.
• W755501454 sameAs 755501454 @default.
• W755501454 citedByCount "21" @default.
• W755501454 countsByYear W7555014542015 @default.
• W755501454 countsByYear W7555014542016 @default.
• W755501454 countsByYear W7555014542017 @default.
• W755501454 countsByYear W7555014542018 @default.
• W755501454 countsByYear W7555014542019 @default.
• W755501454 countsByYear W7555014542020 @default.
• W755501454 countsByYear W7555014542021 @default.
• W755501454 countsByYear W7555014542022 @default.
• W755501454 countsByYear W7555014542023 @default.
• W755501454 crossrefType "journal-article" @default.
• W755501454 hasAuthorship W755501454A5007336688 @default.
• W755501454 hasAuthorship W755501454A5024114335 @default.
• W755501454 hasAuthorship W755501454A5028607728 @default.
• W755501454 hasAuthorship W755501454A5037250149 @default.
• W755501454 hasAuthorship W755501454A5039996379 @default.
• W755501454 hasAuthorship W755501454A5047897531 @default.
• W755501454 hasAuthorship W755501454A5060358335 @default.
• W755501454 hasAuthorship W755501454A5068082042 @default.
• W755501454 hasAuthorship W755501454A5072820678 @default.
• W755501454 hasAuthorship W755501454A5084461306 @default.
• W755501454 hasAuthorship W755501454A5085461814 @default.
• W755501454 hasAuthorship W755501454A5087243487 @default.
• W755501454 hasConcept C115624301 @default.
• W755501454 hasConcept C120665830 @default.
• W755501454 hasConcept C121332964 @default.
• W755501454 hasConcept C178790620 @default.
• W755501454 hasConcept C18168003 @default.
• W755501454 hasConcept C185592680 @default.
• W755501454 hasConcept C18903297 @default.
• W755501454 hasConcept C191897082 @default.
• W755501454 hasConcept C192562407 @default.
• W755501454 hasConcept C198819137 @default.
• W755501454 hasConcept C207114421 @default.
• W755501454 hasConcept C2777299769 @default.
• W755501454 hasConcept C37641323 @default.
• W755501454 hasConcept C44280652 @default.
• W755501454 hasConcept C76804077 @default.
• W755501454 hasConcept C8010536 @default.

• next