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• W75802077 endingPage "376" @default.
• W75802077 startingPage "357" @default.
• W75802077 abstract "Synthetic and natural graphites were metallized with Cu or Ni using a fluidized bed coating and annealing process. With this method, crystalline nanometer-sized metal islands (~ 50 nm diameter) were deposited onto the surface of graphite. Post-metallization, the graphite materials were cycled in lithium coin cells to determine their electrochemical properties in a propylene carbonate (PC) solvent based electrolyte. Better cycling performance (316 mAh/g active graphite, 20 th cycle; 26% irreversible capacity) was obtained with the Cu-coated graphites versus Ni-coated or uncoated types (247 mAh/g, 20 th cycle; 62% irreversible capacity) in a 30% PC blend electrolyte at 50°C. The Cu nanosized deposits help to mediate charge transfer into the graphite particle via improved particle to particle contacts (electrical connectivity) and may contribute to improve kinetics of lithium ion insertion into the graphene layers by assisted Li-Cu interdiffusion. Further, Cu may act as a de-solvation catalyst to remove PCcoordinated molecules from Li cations allowing Li insertion into grapheme layers and overall improved electrochemical performance. Carbon-coated graphite electrodes prepared by a vapor deposition process, show superior performance versus the uncoated graphite in a PC electrolyte system. Coated graphites are under investigation as possible new anodes for high-power lithium-ion battery applications." @default.
• W75802077 created "2016-06-24" @default.
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• W75802077 date "2006-07-07" @default.
• W75802077 modified "2023-09-27" @default.
• W75802077 title "ELECTROCHEMICAL PERFORMANCE OF Ni/Cu-METALLIZED & CARBON-COATED GRAPHITES FOR LITHIUM BATTERIES" @default.
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• W75802077 doi "https://doi.org/10.1007/1-4020-4812-2_28" @default.
• W75802077 hasPublicationYear "2006" @default.
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