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- W75967968 abstract "Preliminary research has indicated that a PBT/PBA co-poly(ester ester) is susceptible to environmental stress cracking in water and in phosphoric acid solution, in both cases at 80 °C. Time-to-Failure creep experiments were initiated to obtain quantitative data. These tests were performed in water and phosphoric acid solutions (pH = 1.6) at 80 °C with notched tensile specimens under constant load (ranging from 0.6-7 MPa). The results have shown that the phosphoric acid solution decreases the lifetime when compared to tests done in water. Both environments decrease the lifetime tremendously when compared to creep tests in air. Comparing the results with the influence of that only hydrolysis on its own has on the degradation of mechanical properties has showed that the results of the Time-to-Failure creep experiments cannot be explained exclusively on the basis of hydrolysis. This confirms the conclusion drawn in our preliminary experiments that the PBT/PBA co-poly(ester ester) is susceptible to stress cracking in both water and phosphoric solution at 80 °C. The influence of water on the environmental stress cracking of the PBT/PBA co-poly(tester ester) can be of a physical and /or chemical nature. The influence of acid, however, must be chemical because just having a small quantity of acid (11.4 g/l) in water will not influence the physical properties but it will decrease the time to failure up to a factor of 10 when compared to pure water." @default.
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- W75967968 date "2003-01-01" @default.
- W75967968 modified "2023-10-16" @default.
- W75967968 title "The Environmental Stress Cracking of a PBT/PBA Co-poly(ester ester)" @default.
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- W75967968 doi "https://doi.org/10.1016/s1566-1369(03)80088-2" @default.
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