Matches in SemOpenAlex for { <https://semopenalex.org/work/W760626711> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W760626711 endingPage "347" @default.
- W760626711 startingPage "343" @default.
- W760626711 abstract "A thermal decomposition of the tert-butoxy radical has been studied in the gas phase over the pressure range of 1-200 torr at using di-tert-butyl peroxide + trimethylsilane mixtures. The relative rate constants were obtained by studying the competitive reactions between tert-butoxy radical decomposition and hydrogen abstraction reaction from trimethylsilane The conventional RRKM calculations were carried out to compare the observed fall-off behavior of the decomposition rate constant with the theoretical predictions using reasonable values of input parameters. In all cases the calculated half-rate pressure were significantly higher than those observed. The failure of RRKM to reproduce the fall-off behavior led us to suggest that not all of vibrational modes contribute to excitation (leading to decomposition) on the same time scale." @default.
- W760626711 created "2016-06-24" @default.
- W760626711 creator A5036462604 @default.
- W760626711 creator A5048186330 @default.
- W760626711 creator A5085373294 @default.
- W760626711 date "1990-01-01" @default.
- W760626711 modified "2023-09-24" @default.
- W760626711 title "The Pressure Dependence of the Rate Constant for the t-Butoxy Radical Decomposition Reaction" @default.
- W760626711 hasPublicationYear "1990" @default.
- W760626711 type Work @default.
- W760626711 sameAs 760626711 @default.
- W760626711 citedByCount "1" @default.
- W760626711 crossrefType "journal-article" @default.
- W760626711 hasAuthorship W760626711A5036462604 @default.
- W760626711 hasAuthorship W760626711A5048186330 @default.
- W760626711 hasAuthorship W760626711A5085373294 @default.
- W760626711 hasConcept C121332964 @default.
- W760626711 hasConcept C124681953 @default.
- W760626711 hasConcept C147789679 @default.
- W760626711 hasConcept C148898269 @default.
- W760626711 hasConcept C160434732 @default.
- W760626711 hasConcept C161790260 @default.
- W760626711 hasConcept C175113610 @default.
- W760626711 hasConcept C178790620 @default.
- W760626711 hasConcept C185592680 @default.
- W760626711 hasConcept C2779439432 @default.
- W760626711 hasConcept C30646810 @default.
- W760626711 hasConcept C35242323 @default.
- W760626711 hasConcept C512968161 @default.
- W760626711 hasConcept C62520636 @default.
- W760626711 hasConcept C75473681 @default.
- W760626711 hasConcept C81022585 @default.
- W760626711 hasConcept C93391505 @default.
- W760626711 hasConcept C97355855 @default.
- W760626711 hasConceptScore W760626711C121332964 @default.
- W760626711 hasConceptScore W760626711C124681953 @default.
- W760626711 hasConceptScore W760626711C147789679 @default.
- W760626711 hasConceptScore W760626711C148898269 @default.
- W760626711 hasConceptScore W760626711C160434732 @default.
- W760626711 hasConceptScore W760626711C161790260 @default.
- W760626711 hasConceptScore W760626711C175113610 @default.
- W760626711 hasConceptScore W760626711C178790620 @default.
- W760626711 hasConceptScore W760626711C185592680 @default.
- W760626711 hasConceptScore W760626711C2779439432 @default.
- W760626711 hasConceptScore W760626711C30646810 @default.
- W760626711 hasConceptScore W760626711C35242323 @default.
- W760626711 hasConceptScore W760626711C512968161 @default.
- W760626711 hasConceptScore W760626711C62520636 @default.
- W760626711 hasConceptScore W760626711C75473681 @default.
- W760626711 hasConceptScore W760626711C81022585 @default.
- W760626711 hasConceptScore W760626711C93391505 @default.
- W760626711 hasConceptScore W760626711C97355855 @default.
- W760626711 hasIssue "4" @default.
- W760626711 hasLocation W7606267111 @default.
- W760626711 hasOpenAccess W760626711 @default.
- W760626711 hasPrimaryLocation W7606267111 @default.
- W760626711 hasRelatedWork W1973811719 @default.
- W760626711 hasRelatedWork W1988619388 @default.
- W760626711 hasRelatedWork W1989771491 @default.
- W760626711 hasRelatedWork W1992888537 @default.
- W760626711 hasRelatedWork W2009562926 @default.
- W760626711 hasRelatedWork W2054284344 @default.
- W760626711 hasRelatedWork W2055321235 @default.
- W760626711 hasRelatedWork W2065976787 @default.
- W760626711 hasRelatedWork W2082785329 @default.
- W760626711 hasRelatedWork W2083157656 @default.
- W760626711 hasRelatedWork W2092557167 @default.
- W760626711 hasRelatedWork W2092575110 @default.
- W760626711 hasRelatedWork W2111713582 @default.
- W760626711 hasRelatedWork W2125199639 @default.
- W760626711 hasRelatedWork W2155991146 @default.
- W760626711 hasRelatedWork W2157065965 @default.
- W760626711 hasRelatedWork W2313160015 @default.
- W760626711 hasRelatedWork W292577933 @default.
- W760626711 hasRelatedWork W2951699489 @default.
- W760626711 hasRelatedWork W2952814989 @default.
- W760626711 hasVolume "11" @default.
- W760626711 isParatext "false" @default.
- W760626711 isRetracted "false" @default.
- W760626711 magId "760626711" @default.
- W760626711 workType "article" @default.