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- W76448890 abstract "The synthesis, characterization, catalytic activity and mechanistic studies of the P2W15Nb3O62 9- supported (l,5-COD)Ir(I)+ complex, (l,5-COD)Ir(I)·P2W15Nb3O62 8-, are described, research that has led to the first bona fide polyoxoanion-supported catalyst. In the first stage of what can be described as the “The Molecular Cookie Cutter Approach to Oxide-Supported Catalysts”, the seven-step synthesis and x-ray crystallographic characterization is described of the novel, custom-designed polyoxoanion P2W15Nb3O62 9-. Second, the synthesis and characterization of the supported (1,5-COD)Ir(I)+ complex, (1,5-COD)Ir(I)·P2W15Nb3O62 8-, is detailed, followed by investigations of this catalytic precursor in oxidation (O2) and reductive (H2) catalytic reactions of cyclohexene. Mechanistic studies are described next, probing the key question “is the true catalyst in fact polyoxoanion-supported?” The results of these simultaneous efforts in four areas is a paradigm for polyoxoanion-supported catalysis, the first class of oxide-supported catalysts that can be fully understood at the atomic level, both structurally and mechanistically." @default.
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- W76448890 date "1994-01-01" @default.
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- W76448890 title "Polyoxoanions in Homogeneous Catalysis: Polyoxoanion-Supported, Atomically-Dispersed Iridium, [(1,5-COD)Ir·P2W15Nb3O62]8-" @default.
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- W76448890 doi "https://doi.org/10.1007/978-94-011-0920-8_20" @default.
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