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- W76451608 abstract "The magnetic susceptibility and resistivity of V${}^{4+}$/V${}^{3+}$ mixed-valence vanadium oxide (hollandite K${}_{2}$V${}_{8}$O${}_{16}$) were measured under pressure. The resistivity measurements show that the charge-order transition temperature (${T}_{mathrm{CO}}$) is suppressed with increasing pressure up to 1 GPa, as observed in many kinds of charge-ordering compounds. At 1 GPa, the pressure dependence of ${T}_{mathrm{CO}}$ suddenly changes its tendency; further compression of the system above 1 GPa leads ${T}_{mathrm{CO}}$ to higher temperatures. This clearly shows an appearance of a new ground state at around 1 GPa. This situation is also revealed by dc-susceptibility measurements: The nonmagnetic ambient ground state suddenly turns into a magnetic state at around 1 GPa. These high-pressure experimental results could be explained as a switching between two kinds of orbital-charge-spin ordered structures." @default.
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- W76451608 date "2011-09-09" @default.
- W76451608 modified "2023-09-30" @default.
- W76451608 title "Electromagnetic properties of hollandite K<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>2</mml:mn></mml:msub></mml:math>V<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>8</mml:mn></mml:msub></mml:math>O<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>16</mml:mn></mml:msub></mml:math>under pressure" @default.
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- W76451608 doi "https://doi.org/10.1103/physrevb.84.115104" @default.
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