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- W765147304 abstract "The electrocatalytic oxidation of N-Acetyl-L-Cysteine (NAC) at a 10-methylphenothiazine (MPT) modified carbon paste electrode (MPT/CPE) was investigated by cyclic voltammetry (CV). Although NAC itself showed a very poor electrochemical response at a carbon paste electrode (CPE), the response could be greatly enhanced at MPT/CPE, which enables a sensitive electrochemical determination of substrate NAC. The reaction rate constant for the catalytic oxidation was evaluated to be(1.59±0.03)×10^(3)(mol•L^(-1))^(-1)•s^(-1) by chronoamperometry (CA). The catalytic oxidation peak current of NAC vs its concentration had a good linear relationship in concentration range of 1.0×10^(-6)~1.3×10^(-3) moL/L with a correlation coefficient of 0.9993, and a detection limit of 8.0×10^(-7) mol/L by linear sweep voltammetry (LSV). This method can be applied to the determination of real samples." @default.
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- W765147304 date "2008-06-10" @default.
- W765147304 modified "2023-09-28" @default.
- W765147304 title "N-乙酰－L-半胱氨酸在10-甲基吩噻嗪修饰碳糊电极上的电催化氧化及电分析" @default.
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