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- W765406225 abstract "The hydrolysis rate of insecticidal buprofezin(IUPAC : tert-butylimino-3-isopropyl-5-phenylperhydro-1,3,5-thiadiazin-4-one) in the range of pH 2.0 and 12.0 have been examined in 15%(v/v) aqueous dioxane at . The hydrolysis mechanism of buprofezin is proposed from the pH-effect, solvent effect(), thermodynamic parameter(=11.12 &, ), rate equation and hydrolysis product, l-isopropyl-3-phenyl urea. General acid catalyzed hydrolysis and specific acid catalyzed() hydrolysis through and A-2(or ) reaction mechanism with orbital-control reaction proceed below pH 8.0 and above pH 9.0, the nucleophilic addition-elimination, mechanism via tetrahedral() intermediate is initiation by general base catalyzed() reaction. Buprofezin was more stable in alkaline () than acid solutions from the sigmoid pH-rate profile. And the half-life() of hydrolysis reaction in neutral aqueous solution(pH 7.0) at was about 3 months." @default.
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- W765406225 date "1998-01-01" @default.
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- W765406225 title "Kinetics and mechanism of hydrolysis of insecticidal buprofezin" @default.
- W765406225 hasPublicationYear "1998" @default.
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