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- W765611547 abstract "The interaction of vanadium(V) with various a-hydroxycarboxylate ligands in aqueous solution at pH 3.2 have been studied by and NMR spectroscopies. From the results it is supposed that vanadates mainly form the octahedral complexes with lactate, 2-hydroxybutyrate, glycerate, and malate. While, vanadates form the trigonal-bipyramidal complexes with glycolate, tartarate, and 2-hydroxy-3-methylbutyrate, and tetrahedral complexes with pyruvate(diol), 2-hydroxyisobutyrate, and 2-hydroxy-3-methylbutyrate. The bipyramidal products are formed as monomeric compounds. The octahedral products are formed as dimeric compounds with no evidence for a significant proportion of the monomeric derivatives. The complexes are mainly formed through the coordination at the carboxylate and the 2-hydroxyl groups of the ligands" @default.
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- W765611547 date "1993-01-01" @default.
- W765611547 modified "2023-09-27" @default.
- W765611547 title "$^{13}C;and;^{51}V $ Nuclear Magnetic Resonance Studies of Vanadium (V)-$alpha$-Hydroxycarboxylate Complexes" @default.
- W765611547 hasPublicationYear "1993" @default.
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