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- W765891425 abstract "New pyrochlore-type phases() were synthesized in the systems: CaO-C-T, CaO-(T)-Z, CaO-(T)--T-Z, 및 CaO-T-S. The starting materials were pressed with the pressure of 200~400 MPa and sintered at 1500~ 155 for 4~8 hours in air and at 1300~ 135 for 5 ~50 hours under oxygen atmosphere. The products were characterized using XRD, SEM/EDS and TEM. In the bulk compositions of CaCe, CaTh,( Gd)(ZrTi)) (Gd)(ZrTi), (G)(ZrTi) and CaTh , pyrochlore was the major phase, together with other oxide phase fluorite structure. In the samples with target compositions CaU및 G)T pyrochlore was not identified, but a fluorite-structured phase was detected. The formation factor as the stable phase depended on crystal chemical characteristics of the actinide and lanthanide elements of the system concerned." @default.
- W765891425 created "2016-06-24" @default.
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- W765891425 date "2002-01-01" @default.
- W765891425 modified "2023-09-23" @default.
- W765891425 title "Synthesis and Crystal Chemistry of New Actinide Pyrochlores" @default.
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