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- W766804730 abstract "Two new trialkoxyethylenes, 1,l-diethoxy-2-methoxy^ ethylene and 1,1,2-tjrimethoxyethylene were synthesized by the methods as given in the literature for the preparation of 1,1,2-triethoxyethylene. All three compounds underwent free radical copolymerization in bulk with monosubstituted electrophilic olefins and electronegatively substituted bicyclobutanes. The copolymers were not alternating but the incorporation of trialkoxyethylenes ranged from 5 to 40%. Conversions and molecular weight were low. Some of the copolymers had low glass transition temperatures and wepe extremely soluble. Electrophilic olefins which co polymerized had e values of 0.2 or greater. Electron deficient disubstituted olefins did not copolymerize for steric reasons. Electron deficient trisubstituted olefins underwent a cycloaddition reaction. Attempts to homopolymerize the trialkoxyethylenes with a cationic initiator resulted in the formation of unidentified addition products." @default.
- W766804730 created "2016-06-24" @default.
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- W766804730 date "1974-01-01" @default.
- W766804730 modified "2023-09-28" @default.
- W766804730 title "Trialkoxyethylenes: a new class of reactive comonomers" @default.
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