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- W767626856 abstract "The effects of added alcohols on the critical micelle concentration(CMC) of cetylpyridinium bromide(CPB) were investigated by the UV-Vis spectrophotometer at the temperature range of 8∼45. The CMC of CPB was increased with the addition of methanol in the whole temperature region studied, while decreased with the addition of ethanol and propanol. The increase of CMC with the addition of methanol may be attributable to the increasing solvent power of the methanol-water mixture, because methanol was scarcely solubilized into the palisade layer of the micelle of CPB. The decrease of CMC with the inclusion of ethanol and propanol may be derived from the solubilization of alcohols into the micelles. On the other hand, the CMC was decreased with the temperature rise in the low-temperature region below about 25, and the CMC was increased in the high-temperature region above that. The thermodynamic parameters () of the micellization of CPB were obtained in some aqueous alcohol solutions. In the whole temperature region (8∼45), the values of were negative, while those of were positive. And in the temperature region below about 25 the values were positive, while in the temperature region above that the values were negative." @default.
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- W767626856 date "1993-01-01" @default.
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- W767626856 title "Thermodynamics of the Micellization of Cetylpyridinium Bromide in Some Aqueous Alcohol Solutions" @default.
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