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- W768966417 abstract "Owing to unique π electron-donating-properties, tetrathiafulvalene (TTF) and its derivatives have been extensively studied over the past decade. In the present work, tetrathiafulvalene acetylene derivative [A-C≡C-TTF-C≡C-A], 4, 4' (5')-bis (4-pyridylethynyl) tetrathiafulvalene (TTF4N), has been synthesized to provide insight into the nature of the donor-acceptor interaction via triple bonds. Spectroscopic, electrochemical and Pb(superscript 2+)-binding studies demonstrate that the TTF unit interacts with electron-accepting pyridine groups via triple bonds, thus leading to intramolecular charge transfer. Moreover, TTF4N show remarkable sensing and coordinating properties toward Pb(superscript 2+)." @default.
- W768966417 created "2016-06-24" @default.
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- W768966417 date "2009-01-01" @default.
- W768966417 modified "2023-09-24" @default.
- W768966417 title "A-C≡C-TTF-C≡C-A型四硫富瓦烯衍生物的合成与性质研究" @default.
- W768966417 doi "https://doi.org/10.7517/j.issn.1674-0475.2009.01.32" @default.
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