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- W77006991 abstract "Sodium sulfate was prepared from sodium chloride by passing sulfur dioxide, steam, and air at atmospheric pressure through a fixed bed impregnated with catalyst. Optimum conditions of temperature, partial pressure of reagent gases, and total flow rate were determined. Several oxides of transition elements were tested for possible catalytic action both alone and with promoters. High yields of sodium sulfate were obtained when oxides were present which could combine in a spinel-type crystal structure. These same oxides alone possessed very little catalytic activity. Evidence of spinel structure was determined in the reaction bed by x-ray powder diffraction. The mineral spinel, magnesium aluminate, possessed unusual catalytic activity. Artificial spinels, prepared from other elements but still having the basic spinel structure, also were found to be active catalysts." @default.
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- W77006991 date "1957-01-01" @default.
- W77006991 modified "2023-09-23" @default.
- W77006991 title "78 Catalytic Formation of Sodium Sulfate" @default.
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- W77006991 doi "https://doi.org/10.1016/s0360-0564(08)60230-8" @default.
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