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• W770404775 endingPage "5398" @default.
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• W770404775 abstract "Two new hybrid organic/inorganic copper oxovanadium diphosphonates [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)]·H2O (1) and [(Cu2(phen)2(O3P(CH2)3PO3)(V2O5)]·C3H8 (2) have been obtained by hydrothermal synthesis. The compounds are monoclinic, and they crystallize in the space group P21/n with cell parameters of a = 11.788(2) Å, b = 17.887(3) Å, c = 14.158(2) Å, and β = 93.99(0)° and in the space group C2/c with cell parameters of a = 11.025(1) Å, b = 18.664(2) Å, c = 15.054(2) Å, and β = 90.06(0)°, respectively. Both compounds present two-dimensional frameworks built up from infinite chains of corner-sharing vanadium tetrahedra and diphosphonate groups connected by copper tetramers for (1) and copper dimers for (2). The remarkable feature of (2) is the encapsulation of propane molecules, stabilized by strong hydrogen bonding between the layers. The magnetic properties of the compounds have been investigated showing antiferromagnetic coupling with Tmax = 64 K for (1) and Curie-like paramagnetic behavior for (2)." @default.
• W770404775 created "2016-06-24" @default.
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• W770404775 date "2006-06-16" @default.
• W770404775 modified "2023-10-18" @default.
• W770404775 title "Two New Hybrid Organic/Inorganic Copper(II)−Oxovanadate(V) Diphosphonates: [Cu₂(phen)₂(O₃PCH₂PO₃)(V₂O₅)(H₂O)]·H₂O and [Cu₂(phen)₂(O₃P(CH₂)₃PO₃)(V₂O₅)]·C₃H₈. Synthesis, Structure, and Magnetic Properties" @default.
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• W770404775 doi "https://doi.org/10.1021/ic060152g" @default.
• W770404775 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16813402" @default.
• W770404775 hasPublicationYear "2006" @default.
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