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- W77151004 abstract "The theory of spi nodal decomposition and nucleation in polymer mixtures is briefly reviewed. For mixtures of linear polymers the standard “gradient-square” theory is valid only for wavelengths exceeding the coil radius. For shorter wavelengths in the linearized theory a treatment based on a random-phase approximation is presented. A Ginzburg criterion is used to show that mean-field theories of nucleation and spinodal decomposition become accurate as the chain length N of the coils becomes large. The equivalence to Ising-models with medium range forces and experimental observations are discussed. Finally the generalization to mixed (interpenetrating) polymer networks is mentioned." @default.
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- W77151004 date "1984-01-01" @default.
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- W77151004 title "KINETICS OF PHASE SEPARATION IN MIXTURES OF LINEAR AND BRANCHED POLYMERS" @default.
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- W77151004 doi "https://doi.org/10.1016/b978-0-444-86912-8.50048-1" @default.
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