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- W772970708 abstract "We report the preparation, structure and magnetic properties of a new pillared complex, copper(II) hydroxy-1,4-butanedisulfonate, <TEX>$Cu_2(OH)_3(O_3SC_4H_8SO_3)_{1/2}$</TEX>. The titled compound was obtained by anion exchange, using copper hydroxyl nitrate <TEX>$(Cu_2(OH)_3NO_3)$</TEX> as the starting material. According to the XRD data, this compound exhibits a pillared layered structure with organic layers tilted between the copper hydroxide layers with a tilt angle of <TEX>$21.8^{circ}$</TEX>. FTIR spectroscopy confirms total exchange of nitrate by the sulfonate and indicates that the sulfonate functions are linked to the copper(II) ions with each aliphatic chain bridging the adjacent hydroxide layers. According to the dc and ac magnetic measurements, the title compound is a metamagnet consisting of spin-canted antiferromagnetic layers, with a Neel temperature of 11.8 K." @default.
- W772970708 created "2016-06-24" @default.
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- W772970708 date "2006-10-20" @default.
- W772970708 modified "2023-09-28" @default.
- W772970708 title "Synthesis, Characterization and Magnetic Properties of a Novel Disulfonate-pillared Copper Hydroxide Cu2(OH)3(DS4)1/2" @default.
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- W772970708 doi "https://doi.org/10.5012/bkcs.2006.27.10.1587" @default.
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