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- W77302475 abstract "A potentiostatic investigation of the cathodic process on an inert electrode in boiling 2 M HNO/sub 3/, i.e., with minimum concentrations of the reduced forms (NO/sub 2/, HNO/sub 2/, N/sub 2/O/sub 3/, NO), has shown the complex reaction between the equilibrium process velocity and the potential. In the absence of HNO/sub 2/ supply to the electrode surface from the bulk of the solution three maxima are exhibited (0.9, 0.65, and 0.2 V) and three minima (0.8, 0.5-0.4, and 0.05 V) of the cathodic process velocity. The complex nature of the polarization curve is maintained in 0.1-8.0 M* boiling HNO/sub 3/ solutions, while the changes in the cathodic reaction velocities may reach a factor of 10/sup 5/ depending on the potential. In their opinion the extreme shape of the polarization curves is caused by changes of the natures of the electrode reactions with potential." @default.
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- W77302475 date "1986-12-01" @default.
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- W77302475 title "Certain characteristics of the cathodic reduction of nitric acid on a platinum electrode" @default.
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