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- W773789075 abstract "The reaction of [Cp∗CrCl2]2 with one or two equivalents of the 3,5-dimethylpyrazolate anion (pzMe2) gave [Cp∗CrCl(μ-pzMe2)(μ-Cl)CrClCp∗] or [Cp∗CrCl(μ-pzMe2)]2 containing bridging 3,5-dimethylpyrazolate anions, respectively. However, with three equivalents of 3,5-dimethylpyrazolate anion, it afforded [Cp∗Cr(pzMe2)(μ-OH)]2 containing two terminally bound 3,5-dimethylpyrazolate anions and two bridging hydroxide anions. With four equivalents of the 3,5-dimethylpyrazolate anion, the mononuclear complex [Cp∗Cr(pzMe2)2(HpzMe2)] containing both the 3,5-dimethylpyrazolate and the neutral pyrazole ligands was isolated. Further, the [Cp∗CrCl2]2 dimer is cleaved when treated with HpzMe2 to give the mononuclear [Cp∗CrCl2(HpzMe2)]. All these complexes are characterized by single crystal X-ray diffraction, magnetic moment, and IR methods." @default.
- W773789075 created "2016-06-24" @default.
- W773789075 creator A5039776318 @default.
- W773789075 creator A5059282283 @default.
- W773789075 date "2015-10-01" @default.
- W773789075 modified "2023-09-25" @default.
- W773789075 title "Synthesis and structural characterization of chromium(III) complexes bearing 3,5-dimethylpyrazolate ligand" @default.
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- W773789075 doi "https://doi.org/10.1016/j.poly.2015.06.029" @default.
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