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- W775100683 abstract "The hydrothermal reaction of ZnO with benzene-1,4-dicar-boxylic acid gave Zn· BDC· 2H2O (1) and Zn·BDC·H2O (2) (BDC = benzene-1, 4-dicarboxylate), respectively. Polymer 1 (C4H4O3Zn0.5) shows a one-dimensional zigzag chain structure built up from the alternate connection of tetrahedral ZnO4 and BDC units. Polymer 2 ( C4H3O2.5 Zn0.5 ) possesses a three-di-mensional framework containing infinite zigzag Zn…Zn…Zn pseudochains generated by five-coordinate zinc centers and a rectangular channel system including three groups of different straight channels along the [001], [010] and [60-1] directions. The two metal-organic polymeric compounds exhibit strong photoluminescent emission bands at 402 nm (λex = 260 nm) (for 1) and at 344 nm and 385 nm (λex=279 nm) (for 2) in the sol-id state at room temperature." @default.
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- W775100683 date "2003-01-01" @default.
- W775100683 modified "2023-10-09" @default.
- W775100683 title "Synthesis, Structure and Photoluminescence of Two Zinc Carboxyl－ate Polymers with Different Coordination Architectures" @default.
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