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- W776898774 abstract "AbstractHyperthermal fluorine atomic beam interaction with PMDA-ODA polyimide (PI) has been studied. It wasfound that CF, CF2 and CF3 groups were formed by reaction of PI with atomic fluorine with an impingementenergy of 11.7 eV. Advancing contact angle of water increases rapidly to 100◦, followed by a slow increasedue to the increase in surface roughness. A gasification reaction of PMDA-ODA was observed under hyperthermal atomic fluorine exposure, and the erosion yield was of the same order of magnitude as that by atomicoxygen. Surface analysis results of atomic fluorine-exposed highly oriented pyrolytic graphite (HOPG) using synchrotron radiation photoelectron spectroscopy showed that the fluorine concentration was limited toonly topmost HOPG (0 0 0 1) layer. From the HOPG experiment, it is revealed that the physical sputteringeffect can be ignored in this hyperthermal atomic beam process and fluorination reaction was restricted onlyto the topmost graphite layer." @default.
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- W776898774 date "2009-04-24" @default.
- W776898774 modified "2023-09-24" @default.
- W776898774 title "Fluorination of PMDA-ODA Polyimide Using Hyperthermal Atomic Fluorine Beams" @default.
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- W776898774 doi "https://doi.org/10.1201/b12248-17" @default.
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