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- W777834171 abstract "Based on solvatochromic and thermochromic data for diphenylpolyenes of the general formula H5C6(CHCH)nC6H5, with n = 1–4, it has been found that their thermochromism is influenced not only by the polarizability of the medium but also by a conformational effect that is at least as strong as that of their solvatochromism. As shown here, the conformational effect enhances the bathochromic band shift caused by lowering the temperature of the solvent. However, such an effect does not occur in structurally rigid diphenylpolyenes. Consequently, Saltiel's isopolarizability approach does not hold in polyenes." @default.
- W777834171 created "2016-06-24" @default.
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- W777834171 date "2015-08-01" @default.
- W777834171 modified "2023-10-16" @default.
- W777834171 title "On Saltiel's isopolarizability approach and its applicability to diphenylpolyenes" @default.
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- W777834171 doi "https://doi.org/10.1016/j.cplett.2015.06.043" @default.
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