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- W77894210 abstract "以荧光光谱和1H NMR谱研究了驱动四苯基卟啉锌(Ⅱ)[Zn(TPP)]-咪唑基尾式卟啉铁(Ⅲ)[Fe(p-ImEPTPP)Cl]超分子自组装的配位键. 研究表明, Fe(p-ImEPTPP)Cl加入到Zn(TPP)二氯甲烷溶液引起的荧光猝灭是前者的尾端咪唑基配位到后者中心离子Zn2+的结果. 在Zn(TPP)/Fe(p-ImEPTPP)Cl体系中分别加入哌啶、咪唑和吡啶等Lewis碱后荧光光谱变化提供了配位键生成的进一步证据. Zn(TPP)/ Fe(p-ImEPTPP)Cl体系的1H NMR谱中的咪唑基质子化学位移的变化, 再次证明了配位键的生成." @default.
- W77894210 created "2016-06-24" @default.
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- W77894210 date "2004-01-01" @default.
- W77894210 modified "2023-09-28" @default.
- W77894210 title "驱动四苯基卟啉锌（II）-咪唑基尾式卟啉铁（III）超分子自组装的配位键：荧光光谱和^1H NMR谱的研究" @default.
- W77894210 hasPublicationYear "2004" @default.
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