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- W783758894 abstract "This study is related to reactivity of dioxygen bridged palladium complexes having -allyl ligands. In this case, new dioxygen bridged palladium complexes were prepared using superoxide ion as an oxygen source. Reactions of the dioxygen palladium complexes prepared in the study were examined in order to clarify the nature of the coordinated dioxygen. Treatments of a solution of the dioxygen bridged palladium complexes in benzene by water, methanol and acetic acid gave hydrogen peroxide as hydroxy-, methoxy-, and acetoxybridged palladium complexes, respectively. The dioxygen bridged palladium complexes reacted also with substitution phenols of salicylaldehyde, 8-hydroxyquinoline and active methylenes of acetylacetone, dimethyl malonate to afford mononuclear complexes of palladium and hydrogen peroxide. The results suggest that dioxygen is coordinated as peroxo in the complexes and behaves as a strong base" @default.
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- W783758894 date "1986-01-01" @default.
- W783758894 modified "2023-09-24" @default.
- W783758894 title "The Study on the Reactivity of Dioxygen Bridged Palladium Complexes Having ${pi}$-Allyl Ligands" @default.
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