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- W78411663 abstract "A theory has been formulated for the one-dimensional adsorption of binary gases. An exact relation between the excess free energy and the composition was obtained. The dependence on surface potential has been collected into a mixing function η, which is related to both the lateral interactions and the adsorbate size. For equal size adsorbates, η will be larger than 1 if it is energetically favorable to have like species together. On the other hand, the mixing of hard rods with unequal size always leads to an η smaller than 1. Negative deviation from an ideal solution will be observed if η<1." @default.
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- W78411663 date "1996-01-01" @default.
- W78411663 modified "2023-09-27" @default.
- W78411663 title "Adsorbed Solution Theory - A One-Dimensional Analysis" @default.
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- W78411663 doi "https://doi.org/10.1007/978-1-4613-1375-5_19" @default.
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