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- W784570711 abstract "The development and optimisation of conditions for oxidative Wacker-type cyclisations followed by establishing the reaction scope are reported. Building upon the achievements in the field of oxidative Wacker-type reactions that has recently gathered interest, hydroxylamines and hydrazines were converted to isoxazolidines and pyrazolidines respectively. Secondary hydroxylamines cyclised yielding syn-isoxazolidines with excellent diastereoselectivities, whereas secondary hydrazines cyclised yielding anti-pyrazolidines but still maintained a high level of diastereoselectivity. Additionally, an enantioselective variant was explored. Isoxazolidines were successfully transformed to the corresponding 1,3-amino alcohols, which were further converted to amino sugar derivatives." @default.
- W784570711 created "2016-06-24" @default.
- W784570711 creator A5084531217 @default.
- W784570711 date "2013-01-01" @default.
- W784570711 modified "2023-09-23" @default.
- W784570711 title "Advances in palladium catalysed Wacker-type oxidative transformations" @default.
- W784570711 hasPublicationYear "2013" @default.
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