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- W78596911 abstract "Montmorillonites used as functional fillers in polymer compounds so far are based on natural sodium bentonites. It has been seen as a scientific challenge to process European calcium bentonites to comparable products. In order to exfoliate the calcium montmorillonite layer packages in a first step, a sophisticated technique was used to transform the calcium into sodium montmorillonite (alkaline activation). A new method to determine the necessary amount of sodium ions for that transformation has been developed and a “Chemical Degree of Activation” as well as a “Technical Degree of Activation” defined. Under the condition of both degrees at their optimum the second step, the organophile modification successfully has been completed with different reagents. Exfoliated montmorillonite platelets were detected by REM pictures. It could be shown that out of selected European calcium bentonite deposits nanofillers with even higher aspect ratios than in older publications reported can be achieved. Criteria for the selection of raw bentonites, the alkaline activation and the achievable aspect ratios have been proposed." @default.
- W78596911 created "2016-06-24" @default.
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- W78596911 date "2015-01-01" @default.
- W78596911 modified "2023-09-30" @default.
- W78596911 title "Processing of calcium montmorillonites for use in polymers" @default.
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- W78596911 doi "https://doi.org/10.1016/b978-0-323-29962-6.00001-7" @default.
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