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- W78702912 abstract "The formation of passive films on Fe90V10 and Fe75Crl5V10 in 1.0 M NaOH is examined by combined electrochemical and surface analytical studies. The electrochemical behaviour was investigated by potentiodynamic polarization curves and the composition of the passive layer has been studied with X-ray Photoelectron Spectroscopy (XPS) with a systematic variation of the electrochemical parameters. Fe90V10 forms a passive layer with an outer Fe(OH)2 layer whereas Fe(III) accumulates within the inner part of the film. Vanadium does not contribute to the outer parts of the film due to its dissolution as vanadate, however, it is accumulated within the inner part of the layer. Fe75Cr15V10 forms a duplex layer with a sequence Fe-oxide / Cr-V-oxide / bulk-metal and thus an accumulation of the Cr and V cations within the centre of the film." @default.
- W78702912 created "2016-06-24" @default.
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- W78702912 date "2006-01-01" @default.
- W78702912 modified "2023-10-16" @default.
- W78702912 title "Passivity of Fe90V10 and Fe75Cr15V10 in Alkaline Media" @default.
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- W78702912 doi "https://doi.org/10.1016/b978-044452224-5/50012-3" @default.
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