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- W787289033 abstract "The reaction of thianthrene cation radical perchlorate with thioxanthene in acetonitrile gave thianthrene and dark reddish thioxanthylium ion instead of thioxanthene cation radical. Addition of aromatic nucleophiles such as anisole, aniline, N,N-diethylaniline, catechol, ethylbenzene, to the above mixture yielded the corresponding thioxanthenes with substituent at 9 position. Reactions with dibenzo-18-crown-6-ether, diphenylmercury, and triphenylphosphine gave similar products. However, reactions with aromatics with electron-withdrawing group were either too slow or inert to such a reaction." @default.
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- W787289033 date "1980-01-01" @default.
- W787289033 modified "2023-09-23" @default.
- W787289033 title "Reaction of Thianthrene Cation Radical Perchlorate with Thioxanthene. Synthesis of Thioxanthene Derivatives" @default.
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