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- W788118938 abstract "The monomer N,N'-bis(3-pyrrol-1-yl-propyl)-4,4'-bipyridinium was electrochemically polymerized on glassy carbon electrode surface. This polymer film electrode has electroactive sites on its bipyridinium ions distributed at the polymer strands. The formal potentials of the electrodes were -0.41V and -0.81V(vs. SSCE) for each step at phosphate buffer(pH=5.70). The diffusion coefficients of the dopants ions into the polymer matrix were and for first and second redox couple, respectively. The rate constants of electron transfer at of the first step was a , which was 22 times higher than one having in the solution. The charge transfer resistance of the polymer film was influenced by the dopant ion of the electrolyte. Thus the resistances were 22.63, 16.81, 12.44 and for , and phosphate buffer, respectively. The reaction order of the electropolymerization was first order and the rate constant of the polymerization was as determined by EQCM method. The G.C./p-BPB type electrode doped with phosphate ions showed a stability and reproducibility in CV procedure over 20 cycles." @default.
- W788118938 created "2016-06-24" @default.
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- W788118938 date "2001-01-01" @default.
- W788118938 modified "2023-09-28" @default.
- W788118938 title "Electrochemistry for Redox Polymer Film of N,N'-bis(3-pyrrol-1-yl-propyl)-4,4'-bipyridinium Ion" @default.
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